NIR-laser-induced selective rotamerization of hydroxy conformers of cytosine.
نویسندگان
چکیده
The relative populations of two amino-hydroxy conformers of cytosine, differing in rotation of the OH group by approximately 180 degrees , were selectively and repeatedly manipulated with narrowband, near-infrared laser light. For cytosine monomers isolated in a low-temperature Ar matrix, laser irradiations at 7013 cm(-1) and at 7034 cm(-1) were found to induce effective transformations of the two conformers into each other.
منابع مشابه
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ورودعنوان ژورنال:
- Physical chemistry chemical physics : PCCP
دوره 12 33 شماره
صفحات -
تاریخ انتشار 2010